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5Cr-0.5Mo Alloy Steels

February 23, 2021

The 5Cr-0.5Mo steel is a member of the heat-resistant chromium-molybdenum (Cr-Mo) alloy steel family. Piping materials made of 5Cr-0.5Mo are widely used for a variety of high pressure and high temperature services such as petroleum cracking facility, coking unit, fertilizer production system, steam facility, and other petrochemical & power applications. It exhibits good resistance to oxidation and creep at elevated temperatures with maximum applicable temperature of 1200°F [649°C]. It is usually used for the construction of power boilers, nuclear facility components, and various pressure vessels. Compared to 1.25Cr-0.5Mo and 2.25Cr-1Mo, the higher chromium content imparts considerable resistance to abrasion and erosion to the 5Cr-0.5Mo alloy steel.

Nominal Chemical Composition

ElementWt. %
C≤0.15
Mn0.30-0.60
S≤0.030
P≤0.030
Si≤0.50
Cr4.00-6.00
Mo0.45-0.65
*The UNS number of 5Cr-0.5Mo is K41545 for all wrought materials (J42045 for castings). P-number: 5B; Group number: 1.

Product Forms & Standards

Product FormStandard & Grade
seamless tubeASTM A213 T5
ASME SA-213 T5
seamless & welded fittingASTM A234 WP5
ASME SA-234 WP5
seamless pipeASTM A335 P5
ASME SA-335 P5
forged pipeASTM A369 FP5
ASME SA-369 FP5
plateASTM A387 Gr.5
ASME SA-387 Gr.5
welded pipeASTM A691 5CR
ASME SA-691 5CR
forgingASTM A336 F5
ASME SA-336 F5
forgingASTM A182 F5
ASME SA-182 F5
castingASTM A217 C5
ASME SA-217 C5
cast pipeASTM A426 CP5
ASME SA-426 CP5
*The 5Cr-0.5Mo alloy steel has two slightly modified versions 5Cr-0.5Mo-Si and 5Cr-0.5Mo-Ti.

Heat Treatment

The 5Cr-0.5Mo alloy steel shall not be furnished in as-rolled condition since without proper heat treatment the metallurgical structure is martensite with very poor toughness and extremely high hardness. Piping materials made of 5Cr-0.5Mo steel shall be furnished in annealed, isothermal-annealed, or normalized and tempered condition.

If normalized and tempered heat treatment is applied, the tempering temperature shall not be less than 1250°F [675°C]. As the rule of thumb, the 5Cr-0.5Mo alloy steel shall be normalized at 950°C, soaking for 30 minutes. After air cooling, the the steel shall be tempered at the optimum temperature of 780°C, soaking for at least 60 minutes. If annealing is applied, the steel shall be soaked at 900°C for 2 hours. It shall be subsequently cooled down to 650°C in furnace atmosphere followed by air cooling.

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